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Chloride Corrosion: Stainless Steel Guide

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    1. Standard Stainless Steels for Chloride Environments

     

    T304 Stainless Steel: Suitable for chloride concentrations 0–200 mg/L.

    T316 Stainless Steel: Tolerates chloride levels <1000 mg/L.

    T317 Stainless Steel: Resists chloride concentrations <5000 mg/L.

     

    Note: Chloride content in hydrostatic test water must not exceed 25 mg/L for stainless steel/nickel alloy pipelines.


    2. Applicable Chloride Environments for Stainless Steels, Super Stainless Steels and Titanium Materials

     

    chloride-corrosion-stainless-steel-guide-01.png

    Refer to Figure 1:

    Low chloride & low temp: 304 (red zone in charts).

    High chloride & high temp: Pure titanium (green zone).

     

    A simplified hierarchy for chloride resistance (low to high):

    304 < 316L < 904L < 254SMO < Pure Titanium (TAI)

     

    3. Duplex Stainless Steels: Chloride Resistance

    The Pitting Resistance Equivalent (PRE) number reflects a material's resistance to chloride-induced pitting corrosion.


    chloride-corrosion-stainless-steel-guide-02.png

    Refer to Fig.2:

    2101/2304/2205/2507 duplex steels outperform 316L, with some matching super austenitics:

    2507 ≈ 254SMO

    2205 ≈ 904L

     

    4. 254SMO vs. 316L in Chloride Environments

     

    Refer to Fig.3:

    316L stainless steel demonstrates significantly inferior chloride pitting corrosion resistance compared to 254SMO. At 60°C, 316L withstands less than 200 ppm chlorides, while 904L resists 8,500 ppm and 254SMO endures up to 15,000 ppm chloride concentration.


    chloride-corrosion-stainless-steel-guide-03.png

    5. Material Selection for Chloride Corrosion in FGD Desulfurization Systems

     

    At 50-70°C, simply match materials to pH and chloride concentration requirements.


    chloride-corrosion-stainless-steel-guide-04.png

    References